马小华，男，博士，研究员。 |
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2009年博士毕业于北京大学高分子化学与物理专业。2009年10月到2018年在沙特阿拉伯国网科技大学（KAUST）从事博士后和博士后研究员的工作。2018年6月被聘为天津工业大学材料科学与工程学院研究员。主要从事有机高性能高分子材料的研究，包括膜材料的分子设计、聚合物以及膜材料的制备和气体分离性能表征等。在相关领域（Angewandte Chemie International Edition, Journal of Materials Chemistry A, Chemical Engineer Journal, Journal of Membrane Science, Macromolecules, Acs Macro Letter, Carbon）等发表学术论文超过100篇，他引超过5000次。以第一专利人身份获得国际发明专利（PCT）5项，参与出版相关方面英文专著二部。
办公地点：天津工业大学科研中心C-209；E-mail：xhuama@tiangong.edu.cn; Tel: 022-83955822
研究领域：
1：高性能碳捕集膜材料的制备以及其结构-性能关系。
2：聚合物分子筛膜材料在高效氧气/氮气、二氧化碳/甲烷、氦气/甲烷、氢气/甲烷分离方面的研究与应用。
3：电子级功能性聚酰亚胺材料以及相关工艺的开发
主讲课程：
《高分子化学及物理》，《材料计算与模拟》，留学研究生课程《Polymer Chemistry》。
部分研究项目
1：国家自然科学基金面上项目：2024.01-2027.12，面向高性能碳捕集膜材料的功能化微孔聚合物分子设计与分离机制研究，50 万，在研，主持。
2：国家自然科学基金面上项目：2021.01-2024.12，高性能富氦聚合物分子筛膜的分子设计与分离机制；64万，结题，主持。
3: 中科院洁净能源创新研究院-榆林学院：横向项目：2022.09-2023.09，零维碳量子点构筑分离膜用于CO2捕获，40 万，在研，参与。
4：杭州依然膜技术有限公司：横向项目：2023.09-2026.09，聚酰亚胺中空纤维脱碳膜材料的开发，100万，在研，主持。
5：东方电气福州创新研究院有限公司：横向项目：DEC1301GG202400120，时间：2025年1月到2025年6月；题目：气体分离膜材料及组件性能表征及测试技术服务，10万，在研，主持。
6：天津市自然科学基金委面上项目：纵向课题：2024年10月到2027年9月；高性能聚酰亚胺中空纤维天然气脱碳膜材料的研究，10万，在研，主持。
7：西安鹏泰航空动力技术有限公司：横向项目：2024年5月到2024年7月；中空纤维膜气体通量测试设备开发；15万，结题，主持。
8：国家自然科学基金青年项目：新型微孔，交联网络型聚酰亚胺膜材料的开发以及在天然气提纯方面的探索，2018/01-2020/12，25 万元, 结题，主持。
9：天津市青年千人启动基金：2018.09-2021.09，100万，结题，主持。
10：天津市科技计划项目：可溶性聚合物分子筛膜材料的分子设计以及在氧气氮气分离中的研究；2019.4-2022.03, 150 万，在研，主持
11：天津工业大学膜国家重点实验室：新型内孔聚合物氧气/氮气分离膜的分子设计与性能研究，2017/12-2019/07，10 万元, 结题，主持。
12：山西煤化所开放基金：新型微孔、交联网络型聚酰亚胺膜材料在CO2/CH4分离方面的探索，2019/01-2020/12，10 万，结题，主持。
部分研究论文，仅列出2012年后的第一作者和通讯作者的文章
1. Luxin Sun, Wei Xu, Hongjun Zhang, Jiachen Chu, Mengtao Wang, Kai Song, Wenjie Wu, Jianxin Li,* Yingge Wang, Ingo Pinnau,* and Xiaohua Ma*In-Situ Formation of Three-Dimensional Network Intrinsic Microporous Ladder Polymer Membranes with Ultra-High Gas Separation Performance and Anti-Trade-Off Effect. Angew. Chem. Int. Ed. 2025, e202420742.
2. Lingyu Liu, Qixuan Li, Luxin Sun, Aqib Riaz, Jianxin Li*, Yingge Wang, Ingo Pinnau*, Xiaohua Ma,* Ultrahigh He enrichment property of carbon molecular sieve membranes by direct fluorination. J Membrane Sci 2025, 717, 123647.
3.Jiachen Chu, Luxin Sun, Han Zhang, Jianxin Li,* Xiaohua Ma,* Enhanced chemical stability and H+/V4+ selectivity of microporous sulfonated polyimide via a triptycene-based crosslinker. J. Power Sources 2025,629, 235964.
4. Mingwei Cai, Jiongcai Chen, Heng Liu, Luxin Sun, Jiahao Wu, Tingting Cui, Shiyang Zhang, Xiaohua Ma*, and Yonggang Min, * Unveiling the Mystery: How TR precursors lead to exceptional gas separation performance in CMSMs, J. Membr. Sci.2025, 713, 123287.
5. Zelong Xu, Qingtan Liu, Lujun Huang, Wenju Zhu*, Xiaohua Ma*. "In-Situ Crosslinking of a Novel Conjugated Dialkynyl-Based Polyimide for High Performance Carbon Molecular Sieve Membrane." J. Membr. Sci. 2024, 697, 122572 (Cited 9).
6. Luxin Sun, Zelong Xu, Lujun Huang, Hong Wang, Han Zhang, Jianxin Li*, Yali Wang, Xiaohua Ma*. "Significantly Enhanced Gas Separation Properties of Membranes by Debromination and Thermal Rearrangement Simultaneously." J. Membr. Sci. 2024, 698, 122619 (Cited 6).
7. Luxin Sun, Jiachen Chu, Hongfen Zuo, Mengtao Wang, Congcong Wu, Aqib Riaz, Lingyu Liu, Jianxin Li*, Xiaohua Ma*. "The Influence of Debromination and Tr on the Microstructure and Properties of CMSMs." Sep. Purif. Tech.2024, 128167. (Cited 3)
8. Aqib Riaz, Lingyu Liu, Zelong Xu, Qingtan Liu, Mohammad Younas, Jianxin Li*, Chen Luo, and Xiaohua Ma*. "Nanocomposite Membranes Comprising Covalent Organic Framework and Polymer of Intrinsic Microporosity for Efficient CO2 Separation." Sep. Purif. Tech.2024, 343, 127175 (Cited 7).
9. Guo, Wei, Luxin Sun, Jiachen Chu, Lingyu Liu, Jianxin Li*, and Xiaohua Ma*. “Huge Improved Gas Separation Performance of Carbon Molecular Sieve Membrane by Forming a Double Crosslinked Polyimide Precursor.”J. Membr. Sci.2024, 711, 123218. (Cited 3)
10: Chao Ye, Chen Luo, Wenhui Ji, Yatao Weng, Jianxin Li*, Shouliang Yi*, Xiaohua Ma*, Significantly enhanced gas separation properties of microporous membranes by precisely tailoring their ultra-microporosity through bromination/debromination, Chem. Eng. J., 2023, 451, 138513 (Cited 34).
11: Wenhui Ji, Huibin Geng, Zishang Chen, Hao Dong, Hideto Matsuyama, Haitao Wang*, Hong Wang, Jianxin Li*, Wenxiong Shi*, Xiaohua Ma*, Facile tailoring molecular sieving effect of PIM-1 by in-situ O3 treatment for high performance hydrogen separation. J. Membr. Sci. 2022,662, 120971 (Cited 19).
12：Kaihua Li, Qixuan Li, Zhenxiao Cai, Yatao Weng, Chao Ye, Wenhui Ji, Jianxin Li*, Bowen Cheng*, Xiaohua Ma*, Microporosity effect of intrinsic microporous polyimide membranes on their helium enrichment performance after direct fluorination, J. Membr. Sci., 2022, 660, 120868 (Cited 15).
13：Junyuan Hua, Xiaohua Ma*, Wenhui Ji, Quan Li, Benqiao He, Zhenyu Cui, Xiaoping Liang, Feng Yan, Jianxin Li*, Unveiling the mechanism of liquid-liquid extraction separation of Li+/Mg2+ using tributyl phosphate/ionic liquid mixed solvents, J. Mol. Liq., 2022, 365, 120080 (Cited 17).
14：Liuyong Mao, Rui Chen, Jintao He, Hongcan Pei, Benqiao He, Xiaohua Ma*, Jianxin Li, Remarkably High Li+ Adsorptive Separation Polyamide Membrane by Improving the Crown Ether Concentration and Electron Density, ACS Sustain. Chem. Eng., 2022, 10, 10047-10056 (Cited 16).
15：Jingtao He, Liuyong Mao, Xiaohua Ma*, Junyuan Hua, Zhenyu Cui, Benqiao He, Hongcan Pei, Jianxin Li*, Highly-Efficient adsorptive separation of Cs+ from aqueous solutions by porous polyimide membrane containing Dibenzo-18-Crown-6, Sep. Purif. Technol., 2022, 299, 121757 (Cited 22).
16：Yatao Weng, Wenhui Ji, Chao Ye, Hao Dong, Zhe Gao*; Jianxin Li, Chen Luo*; Xiaohua Ma*, Simultaneously enhanced CO2 permeability and CO2/N2 selectivity at sub-ambient temperature from two novel functionalized intrinsic microporous polymers. J. Membr. Sci.2021, 120086 (Cited 15).
17: Yatao Weng, Qixuan Li, Jianxin Li, Zhe Gao, Lei Zou, Xiaohua Ma*, Facile Synthesis of Bi-functionalized Intrinsic Microporous Polymer with Fully Carbon Backbone for Gas Separation Application. Sep. Purif. Technol.2021, 119681 (Cited 17).
18: Zhi-Hao Zhang, Shan-Qing Peng, Shumeng Chi, Hanyuan Chen, Lei Fan, Yan Liu, Xiaohua Ma*, Mu-Hua Huang*, Isolated-alkene-linked porous organic polymers (BIT-POPs): facile synthesis via ROMP and distinguishing overlapping signals in solid-state 13C NMR. Polym. Chem.2021, 12, 6745-6754 (cited 9).
19: Xinbo Wang*, Hao Guo, Cong Yu, Yuanju Jing, Zhaobin Han, Xiaohua Ma*, Chenchen Yang, Minghua Liu, Dong Zhai, Daoyuan Zheng, Yupeng Pan, Xiaoju Li, Kuiling Ding, Practical Enantioselective Synthesis of Chiroptical Polymers of Intrinsic Microporosity with Circular Polarized Luminescence. Macromolecules2021, 54, 11180-11186 (cited 18).
20: Xiaohua Ma*, Zhiyang Zhu, Wenxiong Shi, Wenhui Ji, Jianxin Li*, Yingge Wang, Ingo Pinnau*, Unprecedented gas separation performance of a difluoro- functionalized triptycene-based ladder PIM membrane at low temperature, J. Mater. Chem. A, 2021, 9, 5404-5414. (Back Cover, cited 52)
21: Xiaohua Ma*, Kaihua Li, Zhiyang Zhu, Hao Dong, Ja Lv, Yingge Wang, Ingo Pinnau, Jianxin Li*, Bowen Cheng*, Yu Han*, High-Performance Polymer Molecular Sieve Membranes Prepared by Direct Fluorination for Efficient Helium Enrichment, J. Mater. Chem. A, 2021, 9, 18313-18322 (Hot paper, cited 40).
22: Xiulin. Chen, Lei Wu, H. Yang, Yong Qin*, Xiaohua Ma*, Nanwen Li*, Tailoring the Microporosity of Polymers of Intrinsic Microporosity for Advanced Gas Separation by Atomic Layer Deposition, Angew. Chem. Int. Ed., 2021, 60, 17875-17880 (cited 65).
23: Qixuan Li, Zhiyang Zhu, Yuxin Wang, Hong Wang, Jianxin Li*, Xiaohua Ma*, Unprecedented gas separation performance of ITTB/CNT nanocomposite membranes at low temperature by strong interfacial interaction enhanced rigidity, J. Membr. Sci., 2021, 636, 119590 (cited 21).
24: Kaihua Li, Zhiyang Zhu, Hao Dong, Qixuan Li, Wenhui Ji, Jianxin Li*, Bowen Cheng*, Xiaohua Ma*, Bottom up approach to study the gas separation properties of PIM-PIs and its derived CMSMs by isomer monomers, J. Membr. Sci., 2021, 635, 119519. (cited 37)
25: Suangyan Kang, Z. Zhang, Lei Wu, S. Xu, G. Huo, Xiaohua Ma*, Nanwen Li*, Synthesis and gas separation properties of polyimide membranes derived from oxygencyclic pseudo-Tröger's base, J. Membr. Sci., 2021, 119604. (cited 29)
26: Wenhui Ji, Kaihua Li, Wenxiong Shi, Lifeng Bai, Jianxin Li*, Xiaohua Ma*, The effect of chain rigidity and microporosity on the sub-ambient temperature gas separation properties of intrinsic microporous polyimides, J. Membr. Sci., 2021, 635, 119439. (cited 40)
27: Wenhui Ji, Kaihua Li, Yong-Gang. Min, Wenxiong Shi, Jianxin Li*, Xiaohua Ma*, Remarkably enhanced gas separation properties of PIM-1 at sub-ambient temperatures, J. Membr. Sci., 2021, 623, 119091. (cited 48)
28: Hao Dong, Zhiyang Zhu, Kaihua Li, Qixuan Li, Wenhui Ji, Benqiao He, Jianxin Li*, Xiaohua Ma*, Significantly improved gas separation properties of sulfonated PIM-1 by direct sulfonation using SO3 solution, J. Membr. Sci., 2021, 635, 119440. (cited 31)
29: Zhiyang Zhu, Hao Dong, Kaihua Li, Qixuan Li, Jianxin Li*, Xiaohua Ma*, One-step synthesis of hydroxyl-functionalized fully carbon main chain PIMs via a Friedel-Crafts reaction for efficient gas separation, Sep. Purif. Technol., 2021, 262, 118313. (cited 32)
30: Quanji Zhu, Xiaohua Ma*, Hongchang Pei, Jian Li, Feng Yan, Zhenyu Cui, Hong Wang, Jianxin Li*, A highly-efficient lithium adsorptive separation membrane derived from a polyimide-containing dibenzo-14-crown-4 moiety, Sep. Purif. Technol., 2020, 247, 116940. (cited 44)
31: Xiaohua Ma, Holden Lai, Yingge Wang, A. Alhazmi, Yan Xia*, Ingo Pinnau*, Facile Synthesis and Study of Microporous Catalytic Arene-Norbornene Annulation–Tröger’s Base Ladder Polymers for Membrane Air Separation, ACS Macro Lett., 2020, 9, 680-685. (cited 71)
32: Shaolu Li, Zhiyang Zhu, Jianxin Li*, Yunxia Hu*, Xiaohua Ma*, Synthesis and gas separation properties of OH-functionalized Tröger's base-based PIMs derived from 1,1′-binaphthalene-2,2′-OH, Polymer, 2020, 193, 122369. (cited 20)
33: Zhiyang Zhu, Junjie Zhu, Jianxin Li, Xiaohua Ma*, Enhanced Gas Separation Properties of Tröger’s Base Polymer Membranes Derived from Pure Triptycene Diamine Regioisomers, Macromolecules, , 53, 5, 15732020-1584. (cited 55)
34: Yingnan Ma, Zhaopeng Dong, Meng You, Yufeng Zhang, Xianshe Feng, Xiaohua Ma*, Jianqiang Meng*, Formation of thin and continuous MOF membrane with 2-D MOF nanosheets as seeds via layer-by-layer growth. Chem. Commun. 2019.55, 10146-10149. (cited 55)
35: Xiaohua Ma, Yingge Wang, Kexin Yao, Zain Ali, Yu Han and Ingo Pinnau,Pristine and Carboxyl-Functionalized Tetraphenylethylene-Based Ladder Networks for Gas Separation and Volatile Organic Vapor Adsorption, ACS Omega, 2018, 3, 15966–15974. (cited 15)
36: Xiaohua Ma, Ramy Swaidan, Yingge Wang, Chia-en Hsiung, Yu Han and Ingo Pinnau. Highly Compatible Hydroxyl-Functionalized Microporous Polyimide-ZIF-8 Mixed Matrix Membranes for Energy Efficient Propylene/Propane Separation. ACS Appl. Nano Mater., 2108, 1, 3541–3547. (cited 108)
37: Xiaohua Ma and Ingo Pinnau, “Effect of Film Thickness and Physical Aging on “Intrinsic” Gas Permeation Properties of Microporous Ethanoanthracene-Based Polyimides”. Macromolecules. 2018, 51, 1069–1076. (cited 78)
38: Xiaohua Ma, Mahmoud Abdulhamid, Xiaohe Miao and Ingo Pinnau, “Facile Synthesis of a Hydroxyl-Functionalized Tröger’s Base Diamine: A New Building Block for High-Performance Polyimide Gas Separation Membranes”. Macromolecules, 2017, 50, 9569-9576. (cited 84).
39: Xiaohua Ma, Mahmoud A. Abdulhamid, Ingo Pinnau, “Design and Synthesis of Polyimides Based on Carbocyclic Pseudo-Tröger’s Base-Derived Dianhydrides for Membrane Gas Separation Applications”.Macromolecules, 2017, 50, 5850-5857. (cited 71).
40: Xiaohua Ma, Mohsin Mukaddam, Eric Litwiller, Ingo Pinnau. Bifunctionalized Intrinsically Microporous Polyimides with Simultaneously Enhanced Gas Permeability and Selectivity. Macro. Rapid Commu., 2016, 37, 900-904 (Front Cover, Cited: 40).
41: Xiaohua Ma, Ingo Pinnau. A Novel Intrinsically Microporous Ladder Polymer and Copolymers Derived from 1,1′,2,2′-tetrahydroxy-tetraphenylethylene for Membrane-based Gas Separation. Poly. Chem., 2016,7, 1244-1248 (Front Cover, Cited: 56).
42: Xiaohua Ma, Bader Ghanem, Octavio Salines, Eric Litwiller, Ingo Pinnau. Synthesis and Effect of Physical Aging on Gas Transport Properties of a Microporous Polyimide Derived from a Novel Spirobifluorene-Based Dianhydride. Acs Macro Lett., 2015, 4, 231-235. (Cited: 110)
43: Xiaohua Ma, Octavio Salines, Eric Litwiller, Ingo Pinnau. Pristine and Thermally-rearranged Gas Separation Membranes from Novel o-Hydroxyl-Functionalized Spirobifluorene-based Polyimides. Poly. Chem., 2014, 5, 6914-6922. (Front Cover, Cited: 88)
44:Xiaohua Ma, Octavio Salines, Eric Litwiller and Ingo Pinnau. Novel Spirobifluorene- and Dibromospirobifluorene-Based Polyimides of Intrinsic Microporosity for Gas Separation Applications. Macromolecules, 2013, 46, 9618-9624. (Cited: 153)
45: Xiaohua Ma, Raja Swaidan, Baiyang Teng, Hua Tan, Octavio Salines, Eric Litwiller, Ingo Pinnau, and Yu Han. Carbon Molecular Sieve Gas Separation Membranes Based on Intrinsic Microporous Polyimide Precursor.Carbon, 2013, 62, 88-96. (Cited: 178)
46: Xiaohua Ma, Raja Swaidan, Youssef Belmabkhout, Yihan Zhu, Eric Litwiller, Mustapha Jouiad, Ingo Pinnau, and Yu Han. Synthesis and Gas Transport Properties of Hydroxyl-Functionalized Polyimides with Intrinsic Microporosity.Macromolecules, 2012, 45, 3841-3849. (Cited: 249)
部分专利
1 Xiaohua Ma, Ingo Pinnau, Bader Ghanem, “Dianhydrides, Polyimides, Methods of Making Each, and Method of Use”, US Patent, 2013, Pub No, WO/2015/001422.US9840514B2
2 Xiaohua Ma, Bader Ghanem, Ingo Pinnau, “O-hydroxyl-functionalized Diamines, Polyimides, Method of Making Each, and Method of Use”, US patent Application No, 2014, Application No. PCT/IB2015/001396.US20170190842A1,US10240001B2
3 Xiaohua Ma “Dianhydrides, Polyimides derived from biscatecol, methods of making, and method of use”, WO2017085601A1,US20180371168A1,US10604627B2
4 Xiaohua Ma, Ingo Pinnau, Tröger’s Base-Based Monomers, and polymers, methods of making and uses thereof, 2016, WO2017221135A1;US11014932B2
5Xiaohua Ma,Mahmoud Abdul Hamid,Ingo Pinnau.Pseudo Tröger’s base-derived dianhydrides and polyimides derived from pseudo Tröger’s base-derived dianhydrides, 2017, PCT: WO2019012347A1,EP3651878A1
6Xiaohua Ma, Ingo Pinnau, Wang.hong.Lai, Yan. Xia, Intrinsically microporous ladder-type tröger's base polymers, PCT: WO2020058850A1
出版书籍
1. Xiao-Hua Ma, Shi-Yong Yang, Advanced Polyimide Materials, Synthesis, Characterization, and Applications, chapter 6,Polyimide Gas Separation Membranes, Elsevier, 2018, 257-322.
2. Gansheng Liu, Christine Matindi, Mengyang Hu, Xianhui Li, Xiaohua Ma and Jianxin Li, 60 Years of the Loeb-Sourirajan Membrane,Principles, New Materials, Modelling, Characterization, and Applications Chapter 14, Zwitterion-modified membranes for water reclamation, 2022, P349-390