李振环,博士、教授、博士生导师
简介:主要从事树脂合成、树脂改性、以及树脂在过滤分离与阻隔防护中的应用等研究。其中过滤分离与阻隔防护材料是解决能源环境、医疗卫生和生命健康等重大问题的关键技术之一。主持国家自然基金4项、天津市自然基金4项、中石化项目5项(千吨级聚苯硫醚合成与万吨工艺包建设)、山西省科技创新项目1项和中国纺织工业联合会基金2项等。山东易澳科技完成成果转化1项(2000吨碳酸二正丁酯(DBC)的工业化)等,冀中能源峰峰集团技术服务1项。参与完成国家自然基金2项和军工项目1项等。2012年入选天津市高校中青年骨干创新人才,2013年入选天津市“131第一层次人才”,2014入选“山西省科技创新项目”首席专家,2016年入选天津市“131”创新型人才团队带头人,2017年入选天津市高校材料学科领军人才,2019年入选天津市创新人才推进计划中青年科技创新领军人才。2019年获纺织工业联合会科技发明二等奖1项和优秀专利奖1项。承担“纺织行业纤维过滤和防护材料重点实验室”主任、中国纺织品行业协会过滤与分离用纺织品分会名誉会长、中国材料研究学会纤维材料改性与复合技术分会理事会副秘书长。
联系方式:电子邮件:lizhenhuan@tiangong.edu.cn;zhenhuanli1975@aliyun.com.cn; 电话:02283955358。
研究领域:(1)聚芳(苯)硫醚膜材料、聚芳(苯)硫醚改性材料、无熔滴和抗氧化等聚苯硫醚材料、超细纤维制备与应用。(2)呋喃二甲酸聚酯中间体合成、聚合与增粘、呋喃二甲酸聚酯防护材料和医疗卫生材料、包装用呋喃二甲酸聚酯薄膜和分离膜。(3)芳香族聚碳酸酯和脂肪族聚碳酸酯、聚碳酸酯薄膜和医疗材料。(4)电极材料和多相催化材料制备与应用和精细化学品催化合成。
主持科研项目:
1、冀中能源峰峰集团委托项目,聚芳醚新材料开发,2020.1-2021.12,300万,在研,项目负责人;
2、天津市自然科学基金重点项目,2019JCJDJC37300,高强度高韧性无熔缩聚苯硫醚砜纤维的可控制备及应用,2019/04-2022/03,20万,在研主持;
3、国家自然科学基金面上项目,21878231,聚芳硫醚PArSOX膜可控分相、多级孔构筑及选择性分离机理研究,2019.01-2022.12,65万,在研,主持;
4、国家自然科学基金面上项目,21676202,DMC法合成α-氨基酸-N-羧酸酐及其定向酰基化和靶向关环催化机制研究,2017/01-2020/12,64万元,在研,主持;
5、中石化项目,2017008-6,聚苯硫醚技术研究及产品开发,2017/01-2020/12,170万/1630万,在研,主持;
6、中石化项目,216090,工程塑料用聚苯硫醚产品的研究开发,2016/01-2017/12,80万元,结题,主持;
7、天津市131创新团队,纤维过滤材料,2016.01-2019.12,120万在研,主持;
8、天津市自然科学基金重点项目,15JCZDJC37000,中空纤维膜用PPS基树脂制备、膜结构调控极其应用研究,2015/04-2018/03,20万元,结题,主持;
9、中国纺织工业联合会应用基础研究项目,J201406,中空纤维膜用聚苯硫醚基树脂制备、结构调控及其膜应用研究,2015/01-2017/12,20万元,结题,主持;
10、中石化项目,215038,聚苯硫醚聚合机理和聚合过程调控技术研究,2015/01-2016/12,80万元,结题,主持;
11、山东禹城易澳科技有限公司技术转让,超纯碳酸二丁酯合成技术,2014/03-2015/12,180万元,结题,主持;
12、山西省科技创新项目,201401002,聚苯硫醚中空纤维微纳虑膜及膜反应器的规模化制备技术,2014/01-2016/12,300万元,已结题,主持;
13、工信部(军工配套),JPPT-125-5-02,聚苯XX,2014.1-2017.12,726万,结题,参加。
14、国家自然科学基金面上项目,21376177,ArnSnOm靶向催化二甲氧基碳酸双份A二酯合成、缩合及反应机理研究,2013/01-2017/12,80万元,结题,主持;
15、天津市自然基金重点项目,12JCZDJC29800,杂化石墨烯催化纤维素一锅法绿色转化制备5-HMF,2012/04-2015/03,20万元,结题,主持;
16、国家自然科学基金青年项目,21006071,结构单元厚度的MFI片层上复合杂化有机氧化锡的催化剂制备及其强化DmC(1)合成的研究,2011/01-2013/12,19万元,结题,主持;
17、中石化项目,2011100,聚苯硫醚合成工艺优化和工艺包编制,2011/0-2014/12,100万/940万,结题,主持;
18、天津市自然科学基金,09JCYBJC03000,碳酸二甲酯绿色可控合成双酚A型聚碳酸酯的研究,2009/04-2012/03,10万元,结题,主持;
19、中石化项目,2008068,聚苯硫醚树脂合成以及应用技术开发,160/405万元,2008/01-2011/12,结题,主持;
20、阿莱斯国际有限公司委托项目,油墨用酚醛树脂的合成研究,2008/01- 2011/12,30万元,结题,主持。
近五年部分论文简介
(1)YuanGao,KunmeiSu,XiaotianWang,MaliangZhang,ZhenhuanLi(*),KangJia,NGO/PA layer with disordered arrangement hybrid PPS composite membrane for desalination, Desalination, https://doi.org/10.1016/j.desal.2019.114211;
(2)Luyao Gao, Kunmei Su,Tingting Fanb, Zhenhuan Li(*); Study on the structure and properties of PPS/PCNF hybrid membranes and their applications in wastewater treatment, Polymer, 2019, 176,274-282.
(3)Lanlan, Fan; Nanping, Deng; Jing, Yan; Zhenhuan, Li (*); Weimin, Kang; Bowen, Cheng, The recent research status quo and the prospect of electrolytes for lithium sulfur batteries,Chemical Engineering Journal, 2019, 369, 874–897.
(4)Tingting Fan; Jinlei Miao; Zhenhuan Li(*); Bowen Cheng, Bio-inspired robustSuperhydrophobic-superoleophilic polyphenylene sulfide membrane for efficient oil/water separation under highly acidic or alkaline conditions, Journal of Hazardous Materials, 2019, 373, 11-22.
(5)Tingting Fan; Zhenhuan Li (*); Bowen Cheng; Jianxin Li, Preparation, characterization of PPS micro-porous membranes and their excellent performance in vacuum membrane distillation, Journal of Membrane Science 2018, 556,107–117.
(6)Yuan Gao; Kunmei Su; Xiaotian Wang; Zhenhuan Li (*), A metal-nano GO frameworks/PPS membrane with super water flux and high dyes interception, Journal of Membrane Science2019,574,55–64.
(7)Yan Xu; Zhenhuan Li(*); Kunmei Su; TingTing Fan; Lei Cao, Mussel-inspire d modification of PPS membrane to separate and remove the dyes from the wastewater, Chemical Engineering Journal , 2018, 341(3), 371~382.
(8)Zhenhuan Li (*) ; Kunmei Su; Jun Ren; Dongjiang Yang; Bowen Cheng; Chan Kyung Kim; Xiangdong Yao, Direct catalytic conversion of glucose and cellulose, Green Chemistry, 2018. 20, 863~872.
(9)Zhao zhang; Kunmei Su; Zhenhuan Li (*), Carboxylic anhydride synthesis from benzylLglutamate and dimethyl carbonate, Organic Letters, 2019, 21(2), 749~952.
(10)Lei Cao; Xinghai Zhou; Zhenhuan Li (*); Kunmei Su; Bowen Cheng, Nitrogen and fluorine hybridization state tuning in hierarchical honeycomb-like carbon nanofibers for optimized electrocatalytic ORR in alkaline and acidic electrolytes, Journal of Power Sources, 2019, 413, 376~383.
(11)Xinghai Zhou ; Kaihe Song; Zhenhuan Li (*), The excellent catalyst support of Al2O3 fibers with needle-like mullite structure and HMF oxidation into FDCA over CuO/Al2O3 fibers, Ceramics International, 2019, 45(2), 2330~2337.
(12)Yuan Gao; kunmei Su; Zhenhuan Li(*); Bowen Cheng, Graphene oxide hybrid poly(p-phenylene sulfide) nanofiltration membrane intercalated by bis(triethoxysilyl) ethane, Chemical Engineering Journal , 2018, 352(12), 10~19.
(14)Yujun Zhang; Zhen Yin; Jianxin Li; Zhenhuan Li, Nano-V2O5/Ti porous membraneelectrode with enhanced electrochemical activity for the high-efficiency oxidation of cyclohexane, Green Chemistry, 2018,20(17),3944~3953.
(15)Jun Ren; Kaihe Song; Qiang Wang; Jun Li; Yingxiong, Zhenhuan Li, Activation of formyl C-H and hydroxyl O-H bonds in HMF by the CuO (111) and Co3O4 (110) surfaces: A DFT study, Applied Surface Science, 2018, 456, 174~183.
(16)Yongzhi Zhang; Kunmei Su; Zhenhuan Li(*), Graphene oxide composite membranescross-linked with urea for enhanced desalting properties, Journal of membrane science,2018,563,718~725.
(17)Xinghai Zhou; Lei Cao; Maliang Zhang; Weimin Kang; Zhenhuan Li (*), Bowen Cheng, Rapid synthesis of 3D porous nitrogen-doped carbon nanospheres (N-CNSs) and carbon nanoboxes (CNBs) for supercapacitor electrodes, Journal of The Electrochemical Society, 2018,165(5), A918~A923.
(18)Yuan Gao; Bowen Cheng; Kunmei Su, Zhenhuan Li (*), Superhydrophilic poly (p-phenylene sulfide) membrane preparation with acid/alkali solution resistance and its usage in oil/water separation, Separation and Purification Technology, 2018, 192,262~270.
(19)Lei Cao; Zhen-huan Li (*) ; Yu Gu; Dao-hao Li; Kun-mei Su; Dong-jiang Yang; Bo-wen Cheng, Rational design of N-doped carbon nanobox-supported Fe/Fe2N/Fe3C nanoparticles as efficient oxygen reduction catalysts for Zn-air batteries, Journal of Materials Chemistry A, 2017,5,11340~11347.
(20)Xinghai Zhou; Lei Li; Zhenhuan Li (*); Lanlan Fan, Design and fabrication of flexible mesoporous Si-doped Al2O3 ultrafine fibers by electro-blow spinning (EBS) technique, Ceramics International, 2017, 43(13),9729~9737.
(21)ChenyangLi, Zhenhuan Li,(*) LeiCao, BowenCheng, Graphene preparation byphenylmagnesium bromide and its excellent electrical conductivity performance in graphene/poly(p-phenylene sulfide) composites, Industrial & Engineering Chemistry Research, 2016, 55(41), 10860~10867.
(22)ShuangLi, KunmeiSu, ZhenhuanLi,(*) BowenCheng, Selective oxidation of 5-hydroxymethylfurfural with H2O2 catalyzed by a molybdenum complex, Green Chemistry, 2016, 18, 2122~2128.
(23)YuanGao, ZhenhuanLi, KunmeiSu,BowenCheng, Excellent performance of TiO2(B) nanotubes in selective transesterification of DMC with phenol derivatives, Chemical Engineering Journal, 2016, 301, 12~18.
授权专利情况
(1)李振环;樊海彬;苏坤梅,一种聚苯硫醚/石墨烯复合材料的制备方法, 2015.6-2035.6,中国, ZL 2015 1 0350644.8;
(2)李振环;樊海彬;苏坤梅,一种具有自熄性和无熔滴的PPS纤维的制备方法, 2015.9-2035.9,中国, ZL201510631820.5 (专利);
(3)苏坤梅;王超;李振环;牛晓燕,一种离子液体功能化聚苯硫醚多孔膜的制备方法, 2016.8-2036.8,中国, ZL201610666062.5 (专利);
(4)苏坤梅;高原;李振环;牛晓燕,一种聚氨基酸改性聚苯硫醚多孔膜的制备方法, 2016.8-2036.8,中国, ZL201610666063.X (专利);
(5)李振环;李立博;苏坤梅;程博闻,一种2,5-呋喃二甲酸基聚酯纤维的制备方法, 2016.11-2036.11,中国, ZL201611049260.3 (专利);
(6)李振环;曹磊;苏坤梅;程博闻,一种5羟甲基糠醛光催化制备2,5#呋喃二甲酸的方法, 2016.8-2036.8,中国, ZL201610633631.6 (专利);
(7)苏坤梅;李双;李振环,一种5-羟甲基糠醛制备2,5-呋喃二甲酸的方法, 2015.7-2035.7,中国, ZL201510395096.0 (专利);
(8)李振环;程博闻;苏坤梅;丁敏;张磊;杨东江,一种制备5-羟甲基糠醛的方法, 2012.10-2032.10,中国, ZL201210377712.6 (专利);
(9)苏坤梅;李振环;宋焕萌,一种石墨烯负载金属氧化物催化剂的制备方法, 2015. 6-2035.6,中国, ZL201510292763.2 (专利);
(10)苏坤梅;李双;李振环;宋焕萌,一种磺酸和硫醚协同杂化石墨烯催化剂的制备方法,2015.6-2035.6,中国, ZL201510308998.6 (专利);
(11)李振环、苏坤梅、刁乐晨和程博闻,一种合成碳酸二丁酯的方法,ZL201410309109.3.;
(12)李振环、程博闻、苏坤梅和明军,一种中间体二甲氧基碳酸双酚A二酯的制备方法,ZL201110364553.1;
(13)李振环、高媛、苏坤梅和程博闻,一种合成二甲氧基碳酸双酚A二酯的催化剂及其制备方法,ZL201610130596.6;
(14)李振环、刘秀培、苏坤梅、程博闻和何小龙,一种合成二甲氧基碳酸双酚A二酯催化剂的制备方法,ZL201410312867.0;
(15)李振环、孙绪江、程博闻、马志忠、张春林,一种合成低色泽高纯度纤维级聚苯硫醚树脂的方法,ZL201110328395.4;
(16)李振环、孙绪江、程博闻、马志忠、张春林,合成高聚合度聚苯硫醚用对二氯苯的提纯方法,ZL201110277830.5;
(17)程博闻、周旭晨、李振环,一种抗氧化聚苯硫醚树脂的制备方法,ZL201510035644.9.
(18)李振环、梁亚男,一种合成二甲氧基碳酸双酚二酯的多相催化剂的制备方法,ZL2018107096465。